Original Article
  • An Overview on the Physicochemical Properties and Photocatalytic Pollutant Removal Performances of TiO2-incorporated Cementitious Composites

  • J.H. Seo*, H.N. Yoon*, S.H. Kim*, S.J. Bae*, D.I. Jang*, T.G. Kil*, S.M. Park*, H.K. Lee*†

  • * Korea Advanced Institute of Science and Technology

  • TiO2 혼입 시멘트 복합체의 물리∙화학적 특성 및 광촉매 반응을 이용한 오염물 제거 성능에 대한 개요

  • 서준호* · 윤현노* · 김선혁* · 배상진* · 장대익* · 길태건* · 박솔뫼* · 이행기*†

References
  • 1. Ministry of Environment, Air Information in the Seoul Metropolitan Area-Emission by Pollution Sources, 2016.
  •  
  • 2. An, S.W., Jang, J.W., and Park, J.W., “Use of Photocatalyst in Civil & Environmental Engineering,” Prospectives of Industrial Chemistry, Vol. 19, No. 5, 2016, pp. 25-32.
  •  
  • 3. Nagaveni, K., Hegde, M.S., Ravishankar, N., Subbanna, G.N., and Madras, G., “Synthesis and Structure of Nanocrystalline TiO2 with Lower Band Gap Showing High Photocatalytic Activity”, Langmuir, Vol. 20, No. 7, 2004, pp. 2900-2907.
  •  
  • 4. Folli, A., Pade, P., Hansen, T.B., Marco, T.D., and Macphee, D.E., “TiO2 Photocatalysis in Cementitious Systems: Insights into Self-cleaning and Depollution Chemistry,” Cement and Concrete Research, Vol. 42, No. 3, 2012, pp. 539-548.
  •  
  • 5. Jimenez-Relinque, E., Rodriguez-Garcia, J.R., Castillo, A., and Castellote, M., “Characteristics and Efficiency of Photocatalytic Ce-mentitious Materials: Type of binder, Roughness and Microstructure,” Cement and Concrete Research, Vol. 71, 2015, pp. 124-131.
  •  
  • 6. Karapati, S., Giannakopoulou, T., Todorova, N., Boukos, N., Antiohos, S., Papageorgiou, D., Chaniotakis, E., Dimotikali, D., and Trapalis, C., “TiO2 Functionalization for Efficient NOx Removal in Photoactive Cement,” Applied Surface Science, Vol. 319, No. 15, 2014, pp. 29-36.
  •  
  • 7. Serpone, N., “Heterogeneous Photocatalysis and Prospects of TiO2-Based Photocatalytic DeNOxing the Atmospheric Environ-ment,” Catalysts, Vol. 8, No. 11, 2018, pp. 553.
  •  
  • 8. Lee, J.H., Kim, Y.K., and Lee, S.W., “Experimental Study on the Long-term Performance of TiO2 Concrete for Road Structures,” Journal of the Korean Society of Civil Engineers, Vol. 35, No. 3, 2015, pp. 691-698.
  •  
  • 9. Dambournet, D., Belharouak, I., and Amine, K., “Tailored Preparation Methods of TiO2 Anatase, Rutile, Brookite: Mechanism of Formation and Electrochemical Properties,” Chemistry of Materials, Vol. 22, No. 3, 2010, pp. 1173-1179.
  •  
  • 10. Cárdenas, C., Tobón, J.I., García, C., and Vila, J., “Functionalized Building Materials: Photocatalytic Abatement of NOx by Cement Pastes Blended with TiO2 Nanoparticles,” Construction and Building Materials, Vol. 36, 2012, pp. 820-825.
  •  
  • 11. Jayapalan, A.R., Lee, B.Y., and Kurtis, K.E., “Effect of Nano-sized Titanium Dioxide on Early Age Hydration of Portland Cement,” Proceeding of the 3th International Symposium on Nanotechnology in Construction, Berlin, Heidelberg, Germany, MAY. 2009, pp. 267-273.
  •  
  • 12. Gutteridge, W.A., and Dalziel, J.A., “Filler Cement: the Effect of the Secondary Component on the Hydration of Portland Cement: Part I. A Fine Non-hydraulic Filler,” Cement and Concrete Research, Vol. 20, No. 5, pp. 778-782.
  •  
  • 13. Kadri, E.H., and Duval, R., “Effect of Ultrafine Particles on Heat of Hydration of Cement Mortars,” ACI Materials Journal, Vol. 99, No. 2, 2002, pp. 138-142.
  •  
  • 14. Lothenbach, B., Le Saout, G., Gallucci, E., and Scrivener, K., “Influence of Limestone on the Hydration of Portland Cements,” Ce-ment and Concrete Research, Vol. 38, No. 6, pp. 848-860.
  •  
  • 15. Lawrence, P., Cyr, M., and Ringot, E., “Mineral Admixtures in Mortars: Effect of Inert Materials on Short-term Hydration,” Cement and Concrete Research, Vol. 33, 2003, pp. 1939-1947.
  •  
  • 16. Zelic, J., Rusic, D., Veza, D., and Krstulovic, R., “The Role of Silica Fume in the Kinetics and Mechanisms during the Early Stage of Cement Hydration,” Cement and Concrete Research, Vol. 30, No. 10, 2000, pp. 1655-1662.
  •  
  • 17. Gutteridge, W.A., and Dalziel, J.A., “Filler Cement: The Effect of the Secondary Component on the Hydration of Portland Cement: Part 2: Fine Hydraulic Binders,” Cement and Concrete Research, Vol. 20, No. 6, 1990, pp. 853-861.
  •  
  • 18. Osborne, G.J., “Durability of Portland Blast-furnace Slag Cement Concrete,” Cement and Concrete Composites, Vol. 21, No. 1, 1999, pp. 11-21.
  •  
  • 19. Chen, J., Kou, S.C., and Poon, C.S., “Hydration and Properties of Nano-TiO2 Blended Cement Composites,” Cement and Concrete Composites, Vol. 34, No. 5, 2012, pp. 642-649.
  •  
  • 20. Nazari, A., Riahi, S., Riahi, S., Shamekhi, S.F., and Khademno, A., “Improvement the Mechanical Properties of the Cementitious Composite by Using TiO2 Nanoparticles,” Journal of American Science, Vol. 6, No. 4, 2010, pp. 98-101.
  •  
  • 21. Barnes, P., and Bensted, J., “Structure and Performance of Cements,” CRC Press, London, UK, 2002.
  •  
  • 22. Lee, B.Y., Thomas, J.J., Treager, M., and Kurtis, K.E., “Influence of TiO2 Nanoparticles on Early C3S Hydration,” ACI Materials Special Publication, Vol. 267, 2009, pp. 35-44.
  •  
  • 23. Bjornstrom, J., Martinelli, A., Matic, A., Borjesson, L., and Panas, I., “Accelerating Effects of Colloidal Nano-silica for Beneficial Calcium-silicate-hydrate Formation in Cement,” Chemical Physics Letters, Vol. 392, 2004, pp. 242-248.
  •  
  • 24. Sobolev, K., “Modern Developments Related to Nanotechnology and Nanoengineering of Concrete,” Frontiers of Structural and Civil Engineering, Vol. 10, No. 2, 2016, pp. 131-141.
  •  
  • 25. Duan, P., Yan, C., Luo, W., and Zhou, W., “Effects of Adding Nano-TiO2 on Compressive Strength, Drying Shrinkage, Carbonation and Microstructure of Fluidized Bed Fly Ash Based Geopolymer Paste,” Construction and Building Materials, Vol. 106, 2016, pp. 115-125.
  •  
  • 26. Ma, B., Li, H., Li, X., Mei, J., and Lv, Y., “Influence of Nano-TiO2 on Physical and Hydration Characteristics of Fly Ash-cement Sys-tems,” Construction and Building Materials, Vol. 122, 2016, pp. 242-253.
  •  
  • 27. Yang, L.Y., Jia, Z.J., Zhang, Y.M., and Dai, J.G., “Effects of Nano-TiO2 on Strength, Shrinkage and Microstructure of Alkali Acti-vated Slag Pastes,” Cement and Concrete Composites, Vol. 57, 2015. pp. 1-7.
  •  
  • 28. Staub de Melo, J.V., and Triches, G., “Study of the Influence of Nano-TiO2 on the Properties of Portland Cement Concrete for Ap-plication on Road Surfaces,” Road Materials and Pavement Design, Vol. 19, No. 5, 2018, pp. 1011-1026.
  •  
  • 29. Meng, T., Yu, Y., Qian, X., Zhan, S., and Qian, K., “Effect of Nano-TiO2 on the Mechanical Properties of Cement Mortar,” Con-struction and Building Materials, Vol. 29, 2012, pp. 241-245.
  •  
  • 30. Jalal, M., Fathi, M., and Farzad, M., “Effects of Fly Ash and TiO2 Nanoparticles on Rheological, Mechanical, Microstructural and Thermal Properties of High Strength Self Compacting Concrete,” Mechanics of Materials, Vol. 61, 2013, pp. 11-27.
  •  
  • 31. Feng, D., Xie, N., Gong, C., Leng, Z., Xiao, H., Li, H., and Shi, X., “Portland Cement Paste Modified by TiO2 Nanoparticles: A Mi-crostructure Perspective,” Industrial & Engineering Chemistry Research, Vol. 52, No. 33, 2013, pp. 11575-11582.
  •  
  • 32. Lee, N.K., Jang, J.G., and Lee, H.K., “Shrinkage Characteristics of Alkali-activated Fly Ash/slag Paste and Mortar at Early Ages,” Cement and Concrete Composites, Vol. 53, 2014, pp. 239-248.
  •  
  • 33. Chen, J.J., Thomas, J.J., and Jennings, H.M., “Decalcification Shrinkage of Cement Paste,” Cement and Concrete Research, Vol. 36, No. 5, 2006, pp. 801-809.
  •  
  • 34. Lee, B.Y., Jayapalan, A.R., and Kurtis, K.E., “Effects of Nano-TiO2 on Properties of Cement-based Materials,” Magazine of Concrete Research, Vol. 65, No. 21, 2013, pp. 1293-1302.
  •  
  • 35. Zhang, R., Cheng, X., Hou, P., and Ye, Z., “Influence of Nano-TiO2 on the Properties of Cement-based Materials: Hydration and Drying Shrinkage,” Construction and Building Materials, Vol. 81, 2015, pp. 35-41.
  •  
  • 36. Ying, J., Zhou, B., and Xiao, J., “Pore Structure and Chloride Diffusivity of Recycled Aggregate Concrete with Nano-SiO2 and Nano-TiO2,” Construction and Building Materials, Vol. 150, 2017, pp. 49-55.
  •  
  • 37. Mohseni, E., Naseri, F., Amjadi, R., Khotbehsara, M.M., and Ranjbar, M.M., “Microstructure and Durability Properties of Cement Mortars Containing Nano-TiO2 and Rice Husk Ash,” Construction and Building Materials, Vol. 114, 2016, pp. 656-664.
  •  
  • 38. Glass, G.K., Page, C.L., and Short, N.R., “Factors Affecting the Corrosion Rate of Steel in Carbonated Mortars,” Corrosion Science, Vol. 32, No. 12, 1995, pp. 1283-1294.
  •  
  • 39. Seo, J.H., Yoon, H.N., and Lee, H.K., “Photocatalytic Reaction in the Nano-TiO2 Incorporated Cement Exposed to Weathering Carbonation,” In Preparation.
  •  
  • 40. Seo, J.H., Park, S.M., and Lee, H.K., “Evolution of the Binder Gel in Carbonation-cured Portland Cement in an Acidic Medium,” Cement and Concrete Research, Vol. 109, 2018, pp. 81-83.
  •  
  • 41. Macphee, D.E., and Folli, A., “Photocatalytic Concretes – The Interface between Photocatalysis and Cement Chemistry,” Cement and Concrete Research, Vol. 85, 2016, pp. 48-54.
  •  
  • 42. Sofianou, M.V., Trapalis, C., Psycharis, V., Boukos, N., Vaimakis, T., Yu, J., and Wang, W., “Study of TiO2 Anatase Nano and Mi-crostructures with Dominant {001} Facets for NO Oxidation,” Environmental Science and Pollution Research, Vol. 19, 2012, pp. 3719-3726.
  •  
  • 43. Yin, S., Liu, B., Zhang, P., Morikawa, T., Yamanaka, K.I., and Sato, T., “Photocatalytic Oxidation of NOx under Visible LED Light Irradiation over Nitrogen-doped Titania Particles with Iron or Platinum Loading,” The Journal of Physical Chemistry C, Vol. 112, 2008, pp. 12425-12431.
  •  
  • 44. Dalton, J.S., Janes, P.A., Jones, N.G., Nicholson, J.A., Hallam, K.R., and Allen, G.C., “Photocatalytic Oxidation of NOx Gases Using TiO2: a Surface Spectroscopic Approach,” Environmental Pollution, Vol. 120, 2002, pp. 415-422.
  •  
  • 45. Guo, M.Z., Ling, T.C., and Poon, C.S., “Nano-TiO2-based Architectural Mortar for NO Removal and Bacterial Inactivation: Influ-ence of Coating and Weathering Conditions,” Cement and Concrete Composites, Vol. 36, pp. 101-108.
  •  
  • 46. Guo, M.Z., and Poon, C.S., “Superior Photocatalytic NOx Removal of Cementitious Materials Prepared with the White Cement over Ordinary Portland Cement and the Underlying Mechanisms,” Cement and Concrete Composites, Vol. 90, 2018, pp. 42-49.
  •  
  • 47. Park, J.J., and Kwak, J.W., “Characteristics of NOx Removal Efficiency for Photocatalytic Concrete,” Korea Concrete Institute, Vol. 29, 2017, pp. 575-576.
  •  
  • 48. Ballari, M.M., Hunger, M., Hüsken, G., and Brouwers, H.J.H., “NOx Photocatalytic Degradation Employing Concrete Pavement Containing Titanium Dioxide,” Applied Catalysis B: Environmental, Vol. 95, No. 3-4, 2010, pp. 245-254.
  •  
  • 49. Benedix, R., Dehn, F., Quaas, J., and Orgass, M., “Application of Titanium Dioxide Photocatalysis to Create Self-cleaning Building Materials,” Lacer, Vol. 5, 2000, pp. 157-168.
  •  

This Article

Correspondence to

  • H.K. Lee

  • Korea Advanced Institute of Science and Technology

  • E-mail: haengki@kaist.ac.kr