Original Article
  • Effect of Zirconia Particle Addition on Curing Behavior of Phenolic Resins

  • Jaeho Yun*, Hanjun Kim*, Jae Min Lee**, Jong Hee Kim***, Seung Goo Lee**†

  • * Propulsion Technology Team, Daejeon Plant, Hanwha Corporation, Daejeon, 34060, Korea
    ** Department of Organic Materials Engineering, Chungnam National University, Daejeon 34134, Korea
    *** Research Institute for Applied Chemistry and Biological Engineering, Chungnam National University, Daejeon 34134, Korea

  • Zirconia 입자의 첨가가 페놀 수지의 경화거동에 미치는 영향

  • 윤재호*· 김한준*· 이재민**· 김종희***· 이승구**†

  • This article is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/4.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

This study investigated the effect of addition of zirconia(zirconium oxide) powder on the curing behavior of phenolic resins. The heating rate controlled curing and isothermal curing behaviors of the phenol resin according to the content of the zirconia powder were analyzed. The viscosity and thermal decomposition characteristics of the phenolic resin with the zirconia content were also examind. From the DSC analysis, the degree of cure and the rate of cure were obtained. Finally, the activation energy for the cure reaction were calculated from the DSC data of the zirconia added phenolic resin. As a found, the higher the zirconia content, the longer the curing was delayed and the greater the activation energy required for curing. Additionally, the TGA result that as the content of zirconia increased, less weight loss was observed. The surface tackiness of the Carbon/Phenol prepreg was partially changed according to the zirconia content, but had no significant effect.


본 연구는 Zirconia(zirconium oxide) 입자가 페놀수지 경화거동에 미치는 영향을 조사하였다. Zirconia 입자의 함량에 따른 페놀수지의 승온 및 등온 경화 거동을 분석하였다. Zirconia 함량을 달리한 페놀수지의 점도 및 열분해 특성을 조사하였다. DSC 분석으로부터 경화도와 경화율을 구하였다. 마지막으로 Zirconia 입자가 첨가된 페놀수지의 DSC 데이터로부터 경화 반응에 대한 활성화 에너지를 계산하였다. 그 결과 zirconia 함량이 높을수록 경화가 지연되고 경화에 필요한 활성화에너지가 더 커지는 경향이 나타났다. 또한 TGA를 이용한 열분해 분석 결과 Zirconia의 함량이 증가할수록 더 적은 중량감소가 관찰됐다. Carbon/Phenol 프리프레그의 표면 점착성은 Zirconia 함량에 따라 부분적으로 변화하였으나 유의한 영향은 없었다


Keywords: 페놀수지(Phenolic resin), 산화물 첨가제(Oxide additive), 프리프레그(Prepreg), 경화반응(Cure reaction), 활성화에너지(Activation energy

This Article

Correspondence to

  • Seung Goo Lee

  • ** Department of Organic Materials Engineering, Chungnam National University, Daejeon 34134, Korea

  • E-mail: lsgoo@cnu.ac.kr